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Determination of volatile halogenated hydrocarbons in exhaust gases from fixed sources of pollution - Gas bag sampling - Gas chromatography method
Date: 2025-08-27Read: 1

Fixed pollution source exhaust gas

Determination of volatile halogenated hydrocarbons

Air bag sampling——Gas chromatography method

Experimental plan basisHJ 1006-2018 launched
MANUFACTURE

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Volatile halogenated hydrocarbons: a hidden threat in the fields of environment and health

Volatile halogenated hydrocarbons(Volatile Halohydrocarbons,VHHs)As a type of organic pollutant widely present in the environment, it has long been highly concerned by the scientific community and environmental regulatory authorities due to its high volatility, bioaccumulation, and potential toxicity. These compounds are usually formed by covalent bonding between carbon, hydrogen elements and halogen atoms such as chlorine, bromine, and fluorine. They have diverse structures and are widely used in industrial solvents, refrigerants, disinfectants, and chemical raw material synthesis.

With the acceleration of global industrialization and urbanization, the use and emissions of volatile halogenated hydrocarbons have sharply increased. They can enter the atmosphere, water bodies, and soil environment through industrial waste gas emissions, sewage leaks, waste incineration, and other pathways, forming a complex multi-media pollution network. Volatile halogenated hydrocarbons in the atmosphere not only participate in the formation of photochemical smog, affecting regional air quality, but also destroy the ozone layer in the stratosphere, exacerbating global climate change; Halogenated hydrocarbons in water and soil can be transmitted through bioaccumulation in the food chain, ultimately posing a threat to human health. Some typical volatile halogenated hydrocarbons, such as carbon tetrachloride and vinyl chloride, have been identified by the International Agency for Research on Cancer(IARC)Listed as carcinogens or suspected carcinogens, long-term exposure may cause liver and kidney damage, and even trigger genetic mutations and cancer.

The detection method for volatile halogenated hydrocarbons in fixed pollution source exhaust gas is mainly based on gas chromatography technology. The following are the core detection process and key points (taking HJ 1006-2018 standard as an example)

1、 Sampling principle:

Using gas chromatography(GC)Separate volatile halogenated hydrocarbons using an electron capture detector(ECD)Or mass spectrometer detector(MS)Quantitative. Volatile halogenated hydrocarbons in exhaust gases from fixed pollution sources can be collected using gas bags, directly injected, separated by gas chromatography, and detected by electron capture detectors(ECD)Detection, qualitative based on retention time, quantitative based on external standard method.

2、 Specific testing steps:

1.1GC3900ProGas chromatograph: with split flow/Non diversion injection port, electron capture detector(ECD)

图片2.png

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1.2 Quartz capillary column:30 m×0.25 mm×1.40 μmThe fixed phase is6%Cyanopropyl phenyl and94%Dimethyl polysiloxane. Other equivalent capillary columns can also be used.

1.3 Airbag: Polyfluoroethylene(PVF)Material or other equivalent material airbag.

1.4 Sampling tube: made of hard glass or polyethylene material. The inner diameter should be greater than6 mm, and should be accompanied by a heatable to120℃the aboveInsulation jacket.

1.5 Smoke and dust sampler: equipped with modules for measuring the moisture content and temperature of flue gas, the instrument performance meets the requirementsHJ/T 48The requirements.

1.6 Gas dilution device: accuracy reaches or exceeds2%.

1.7 Oven: Temperature can reach130℃, accuracy±1℃.

1.8 Airtight syringe:1.0 ml.

1.9 Commonly used instruments and equipment in general laboratories.

2. Standard solution configuration

Standard series for preparing target compounds such as chloromethane, dichloromethane, and carbon tetrachloride using methanol or carbon disulfide (e.g0.1、0.5、1.0、5.0The10.0 mg/L)Blow off with nitrogen to produce standard gas.

3. Sample analysis

Sample airbag: directly taken1mLGas injection into chromatograph.

Adsorption tube sample: After desorption with nitrogen or solvent, the sample is taken.

4. Quantitative analysis

Using the external standard method, based on the standard curve (peak area)-Calculate the concentration of each component in the sample.

3、 Functional halogenated hydrocarbon curve

图片3.png


Volatile halogenated hydrocarbon analysis data

serial number

name

Retention time (min)

peak area

Concentration (g/L)

Work curve equation

correlation coefficient

1

chloromethane

7.4274

28.0904

10.7296

Y= 2.61802X

0.99774

2

vinyl chloride

7.9317

1.3276

11.4169

Y= 0.11628X

0.99377

3

Methyl bromide

9.4287

50.9046

1.9993

Y= 25.46135X

0.99828

4

Bromoethane

15.0699

28.1265

1.8718

Y= 15.02655X

0.99780

5

Chloropropene

16.4852

25.0450

1.9162

Y= 13.06988X

0.99801

6

Dichloromethane

17.4304

23.4332

1.9477

Y= 12.03124X

0.99866

7

Chloroprene

22.5481

2.9196

0.1785

Y= 16.35928X

0.99949

8

CHCl₃

26.2339

9.3313

0.0206

Y= 4.53273e2X

0.99750

9

carbon tetrachloride

27.2191

5.9882

0.0027

Y= 2.22959e3X

0.99789

10

1,2-Dichloroethane

28.1835

37.7265

1.9879

Y= 18.97820X

0.99101

11

trichloroethylene

30.1556

15.4139

0.0184

Y= 8.35860e2X

0.99691

12

1,2-Dichloropropane

30.9608

41.7603

1.9850

Y= 21.03791X

0.99060

13

Epichlorohydrin

33.2334

133.8046

8.8767

Y= 15.07375X

0.99359

14

tetrachloroethylene

36.3683

7.1837

0.0018

Y= 3.93923e3X

0.99841