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E-mail
2577895416@qq.com
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Phone
19867723812
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Address
3rd Floor, Building C, Yisai Technology Park, No. 365 Baotian 1st Road, Bao'an District, Shenzhen
Shenzhen Huapu General Technology Co., Ltd
2577895416@qq.com
19867723812
3rd Floor, Building C, Yisai Technology Park, No. 365 Baotian 1st Road, Bao'an District, Shenzhen
HP2000-GCHot cracking detachment apparatus
cope withRoHS2.0add4Solution for screening ortho benzene
On June 4, 2015, the Official Journal of the European Union (OJ) issued the revised RoHS 2.0 Directive (EU) 2015/863, which added four phthalates to the RoHS 2.0 restricted substances list on the basis of the original six RoHS substances (lead, cadmium, mercury, hexavalent chromium, polybrominated biphenyls, and polybrominated diphenyl ethers), bringing the total number of controlled substances in RoHS 2.0 to 10.
| substance name | CAS NO. | Main applications in electronic and electrical equipment |
| Di (2-ethylhexyl) phthalate (DEHP) | 117-81-7 | Mainly used as a plasticizer for PVC, PVC is used as an insulator in electronic and electrical equipment such as cables and wires. A small amount of DEHP is used for other non polymer purposes, such as electrolytes for ceramics or capacitors in electronic products. |
| Butyl benzyl phthalate (BBP) | 85-68-7 | Mainly used in conjunction with other plasticizers in PVC components such as cables, sockets, pipes, shock absorbers, and also used in some non polymer materials such as paint and glue |
| Dibutyl phthalate (DBP) | 84-74-2 | Mainly used as a plasticizer in PVC flooring, it may exist in synthetic leather, textile coatings, PVC materials, printing inks, sealants, and adhesives in electronic and electrical equipment |
| Diisobutyl phthalate (DIBP) | 84-69-5 | Used as a plasticizer for PVC, a substitute for DBP, and also as a plasticizer for cellulose resin, vinyl resin, nitrile rubber, and chloroprene rubber. |
According to the RoHS 2.0 testing standard, production enterprises need to purchase relevant equipment for rapid screening of raw materials, material self inspection, internal quality control, customer factory inspection, etc. (instruments required for conventional configuration: GCMS+EDXRF spectrometer). However, purchasing these equipment can easily cost millions, which puts great pressure on many enterprises. Without screening, there will be huge hidden dangers in product production, and enterprises cannot control whether their products meet the standards; Based on the importance of internal screening in enterprises and the huge investment required for purchasing equipment, Jingu Keyi has developed a new solution specifically for the rapid screening needs of four types of ortho benzene in Rohs2.0: HP3000-GC micro cracking release ortho benzene rapid screening solution
This HP2000-GC system can detect 20 types of ortho benzene, meeting the needs of ortho benzene detection. In addition to ortho benzene detection, this system can also be used for flame retardants, organic solvent residues, polymer materials, volatile organic compounds in materials, and more, with powerful functions!
Shenzhen Hangsheng Precision Connector Co., Ltd. (connector enterprise) purchases 1 set of HP2000-GC ortho benzene detector
Part 2: Comparative Analysis of Three Current RoHS2.0 Solutions
| RoHS2.0 Ten Controlled Substances | PY+GCMS method (sample preparation time 40 minutes) | Liquid chromatography method (sample preparation time 100 minutes) | ☆ TP30-GC micro cracking desorption gas phase method (sample preparation time 20 minutes) ☆ | |||||||
| Equipment procurement cost | Usage fee | personnel cost | Equipment procurement cost | Usage fee | personnel cost | Equipment procurement cost | Usage fee | personnel cost | ||
| Rohs1.0 6 items | lead | Shimadzu/Hitachi ED-XRF(35万) | 50000 yuan/year | 200000 yuan/year (2 professional inspectors) | Shimadzu/Hitachi ED-XRF(35万) | 50000 yuan/year | 160000 yuan/year (2 professional inspectors) | Tianrui/Huawei EDX (100000 yuan) | 10000 yuan/year (no other consumables required) | 60000 yuan/year (1 full-time inspector can operate 2 instruments) |
| mercury | ||||||||||
| cadmium | ||||||||||
| chromium | ||||||||||
| Polybrominated biphenyls | ||||||||||
| Polybrominated diphenyl ether | ||||||||||
| Rosh2.0 Add 4 new ortho benzenes | DBP BBP DEHP DIBP | Shimadzu PY+GCMS (1.5 million) | 100000 yuan/year | HPLC (180000) | 100000 per year (requires a large amount of reagents and declaration of hazardous materials) | TP30-GCMicro cracking desorption gas chromatography (400000) | 5000Yuan/year (only a small amount of quartz injection tube needs to be replaced) | |||
| Procurement cost and usage cost | 185ten thousand | 15Ten thousand per year | 20Ten thousand per year | 53ten thousand | 15ten thousand | 16ten thousand | 50ten thousand | 1.5Ten thousand per year | 6Ten thousand per year | |
| Sample practicality | IECThe standard clearly states that only soluble solid samples can be subjected to ultrasonic extraction, while difficult to dissolve or insoluble polymer samples cannot be subjected to ultrasonic extraction. (Generally, 30% of polymer samples in factories are insoluble or difficult to dissolve, in other words, 30% of samples may be misjudged during the sampling process.) | IECThe standard clearly states that only soluble solid samples can be subjected to ultrasonic extraction, while difficult to dissolve or insoluble polymer samples cannot be subjected to ultrasonic extraction. (Generally, 30% of polymer samples in factories are insoluble or difficult to dissolve, in other words, 30% of samples may be misjudged during the sampling process.) | Polymer samples that are soluble, insoluble, or difficult to dissolve are all acceptable (99% of samples from regular factories), and there will be no misjudgment | |||||||
| 70% | 70% | 99% | ||||||||
| Separation effect | 4Good separation effect of ortho benzene | There are two neighboring benzene compounds that cannot be separated, which affects the results | 4Good separation effect of ortho benzene | |||||||
| Is there any standard | Compliant with IEC62321 standard | N/A | Compliant with IEC62321-8 standard | |||||||
| How many things can be done every day | Process 30 samples per day | Process around 5-7 samples per day Each sample should be sonicated for at least 2 hours, and the sample should be made for 30 minutes (sonication for 2 hours may not necessarily reveal the presence of ortho benzene in many samples) | Process over 50 samples per day No need for sample pre-treatment, the sample making process is fully automated, and each sample takes 20 minutes to complete | |||||||
| Applying for a wastewater and exhaust gas discharge permit? | Need (complicated procedures) 1Requires a large amount of reagents (such as acetoneAcetonitrile and other reagents require reporting before use, and a professional laboratory needs to be established to pass the environmental impact assessment by regulatory authorities 2A large amount of wastewater and waste liquid are generated, which cannot be treated by oneself. It is necessary to hire a professional hazardous waste company to handle it, which is costly and cumbersome, and requires applying for a hazardous waste discharge permit
| Need (complicated procedures) 1Requires a large amount of reagents (such as acetoneAcetonitrile and other reagents require reporting before use, 2A large amount of wastewater and waste liquid are generated, which cannot be treated by oneself. It is necessary to hire a professional hazardous waste company to handle it, which is costly and cumbersome, and requires applying for a hazardous waste discharge permit
| No need This plan does not contain any reagents and will not produce any wastewater or waste liquid, Set up an environment with a console and air conditioning installed | |||||||
| feature | High procurement cost complicated operation High operation and maintenance costs in the later stage | The pre-processing is too complicated The operator's operation has a significant impact on the results The sample preparation time is too long and does not have the ability to quickly screen | Low procurement cost; The screening process is simple and fast; Low operation and maintenance costs in the later stage | |||||||
Part Three, Instrument Accuracy and Reliability Test:
Experimental section: Instruments and consumables
1. Gas chromatograph with dual EPC control;
2. HP3000-GC thermal cracking desorption instrument (cracking desorption temperature 200 ℃ -650 ℃);
3. Chromatography workstation (with reverse control function);
4. Capillary ortho benzene column;
5. Nitrogen hydrogen air source;
6. One ten thousandth scale;
Pre processing procedure:
This method does not require pre-treatment. The consumables include a 2.5cm quartz tube, quartz wool, and pre-treatment column. Place the solid sample in the middle of the quartz tube, fix both ends with quartz wool, and then place the prepared sample tube into the heating chamber.
Analysis conditions
Micro cracking program heats up from 200 ℃ to 450 ℃
Micro pyrolysis time 2 minutes
Injection method: Split injection
Liquid injection volume: 1 ul
Solid injection volume: below 5mg
Injection port temperature: 250 ℃
FID detector temperature: 300 ℃
Program heating up to 50 ℃ (hold for 1 minute), increasing to 400 ℃ at a rate of 20 ℃ per minute (hold for 10 minutes)
Name and retention time of each component
| name | abbreviation | retention time | Time window strip | remark |
| Diisobutyl phthalate | DIBP | 8.524 | 0.05 | |
| Dibutyl phthalate | DBP | 9.041 | 0.05 | |
| Butyl benzyl phthalate | BBP | 10.941 | 0.05 | |
| Di (2-ethylhexyl) phthalate | DEHP | 11.949 | 0.05 |
Results and Discussion:

Standard curve and linear range (detection limit)
Prepare DIBP standard solutions with concentrations of 50ppm, 100ppm, 250ppm, 500ppm, and 1000ppm. Plot standard curves with concentration as the x-axis and quantitative component peak area as the y-axis. The standard curves and linear correlation coefficients are shown below.

The following table shows the comparison of peak height and peak area for 5 different concentration standard samples:
| Concentration (ppm) | Peak height (pA) | Peak area (A) |
| 50 | 2038.7 | 8472.5 |
| 100 | 2829.6 | 12607.7 |
| 250 | 5720.6 | 24674.0 |
| 500 | 12090.8 | 53037.4 |
| 1000 | 24747.2 | 120759.3 |
The detection limit for each component calculated based on a 3x signal-to-noise ratio is 25ppm
Repetition (precision experiment)
The repeatability determination was conducted at the detection limit concentration, and the results are shown below.
| RSD% | ||
| DIBP | Peak Height | peak area |
| 1 | 944.8 | 3484.2 |
| 2 | 1007.3 | 3638.8 |
| 3 | 903.2 | 3167.9 |
| 4 | 1205.6 | 4227.6 |
| RSD%=5.24 | ||
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