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HP2000-GCHot cracking detachment apparatus

cope withRoHS2.0add4Solution for screening ortho benzene

On June 4, 2015, the Official Journal of the European Union (OJ) issued the revised RoHS 2.0 Directive (EU) 2015/863, which added four phthalates to the RoHS 2.0 restricted substances list on the basis of the original six RoHS substances (lead, cadmium, mercury, hexavalent chromium, polybrominated biphenyls, and polybrominated diphenyl ethers), bringing the total number of controlled substances in RoHS 2.0 to 10.

substance name

CAS NO.

Main applications in electronic and electrical equipment

Di (2-ethylhexyl) phthalate (DEHP)

117-81-7

Mainly used as a plasticizer for PVC, PVC is used as an insulator in electronic and electrical equipment such as cables and wires. A small amount of DEHP is used for other non polymer purposes, such as electrolytes for ceramics or capacitors in electronic products.

Butyl benzyl phthalate (BBP)

85-68-7

Mainly used in conjunction with other plasticizers in PVC components such as cables, sockets, pipes, shock absorbers, and also used in some non polymer materials such as paint and glue

Dibutyl phthalate (DBP)

84-74-2

Mainly used as a plasticizer in PVC flooring, it may exist in synthetic leather, textile coatings, PVC materials, printing inks, sealants, and adhesives in electronic and electrical equipment

Diisobutyl phthalate (DIBP)

84-69-5

Used as a plasticizer for PVC, a substitute for DBP, and also as a plasticizer for cellulose resin, vinyl resin, nitrile rubber, and chloroprene rubber.

According to the RoHS 2.0 testing standard, production enterprises need to purchase relevant equipment for rapid screening of raw materials, material self inspection, internal quality control, customer factory inspection, etc. (instruments required for conventional configuration: GCMS+EDXRF spectrometer). However, purchasing these equipment can easily cost millions, which puts great pressure on many enterprises. Without screening, there will be huge hidden dangers in product production, and enterprises cannot control whether their products meet the standards; Based on the importance of internal screening in enterprises and the huge investment required for purchasing equipment, Jingu Keyi has developed a new solution specifically for the rapid screening needs of four types of ortho benzene in Rohs2.0: HP3000-GC micro cracking release ortho benzene rapid screening solution

This HP2000-GC system can detect 20 types of ortho benzene, meeting the needs of ortho benzene detection. In addition to ortho benzene detection, this system can also be used for flame retardants, organic solvent residues, polymer materials, volatile organic compounds in materials, and more, with powerful functions!

Part: Introduction to HP3000-GC ROHS2.0 ortho benzene solution

HP3000-GCThe plan has the following advantages:
1Short sample making time20 minutes/sample preparation time * quick screening needs of enterprise users;
2No waste gas or liquid is generated:This type requires no reagents, no pre-treatment, and does not produce waste gas or liquid;
3. Low cost of use:No pre-treatment, no need for reagents and consumables, with a usage cost of less than 3000 yuan per year;
4. Direct injection, simple operation:Direct solid or liquid injection, with results obtained from five operations, can be operated by production line workers;
5. Built in standard curve:More intuitive judgment of whether the material exceeds the standard of ortho benzene (technical);
6. Suitable for 100% polymer materials:Chemical methods are only suitable for 70% of materials, while HP3000-GC is suitable for 100% of materials
7No need for a professional laboratory environmentOnly a regular operating space with air conditioning power supply is needed for installation and use.

Successful cases of large clients in this program:
Shenzhen Weifu Communication Technology Co., Ltd. (Huawei's first tier supplier) purchases 1 set of HP2000-GC ortho benzene detector
Shenzhen Zhaochi Co., Ltd. (listed company) purchases 1 set of HP3000-GC ortho benzene detector
Guangdong Rifeng Cable Co., Ltd. (listed company) purchases 1 set of HP3000-GC ortho benzene detector
Shenzhen Zhongyuan Electronics Co., Ltd. (Oppo supplier) purchases 1 set of HP2000-GC ortho benzene detector
Xielong (Dongguan) Plastic Electronics Co., Ltd. (Nintendo supplier) purchases 1 set of HP2000-GC ortho benzene detector
Shenzhen Shengjiali Electronics Co., Ltd. (Shenzhen headphone speaker manufacturer) purchases 1 set of HP2000-GC ortho benzene detector
Sichuan Mianyang Changhong Mold&Plastic Co., Ltd. (* enterprise) purchases 1 set of HP2000-GC ortho benzene detector
Tongxingda Electronics Co., Ltd. (listed company) purchases 1 set of HP3000-GC ortho benzene detector
Zhongtianxun Communication Co., Ltd. (antenna enterprise) purchases 1 set of HP2000-GC ortho benzene detector
Jiangsu Chenyang Electronics Co., Ltd. (connector OEM enterprise) purchases 1 set of HP2000-GC ortho benzene detector
Jiangxi Lijing Innovation Technology Co., Ltd. (a subsidiary of Lixun Precision) purchases 1 set of HP3000-GC ortho benzene detector

Shenzhen Hangsheng Precision Connector Co., Ltd. (connector enterprise) purchases 1 set of HP2000-GC ortho benzene detector

Part 2: Comparative Analysis of Three Current RoHS2.0 Solutions

RoHS2.0 Ten Controlled Substances

PY+GCMS method (sample preparation time 40 minutes)

Liquid chromatography method (sample preparation time 100 minutes)

☆ TP30-GC micro cracking desorption gas phase method (sample preparation time 20 minutes) ☆

Equipment procurement cost

Usage fee

personnel cost

Equipment procurement cost

Usage fee

personnel cost

Equipment procurement cost

Usage fee

personnel cost

Rohs1.0

6 items

lead

Shimadzu/Hitachi

ED-XRF(35万)

50000 yuan/year

200000 yuan/year (2 professional inspectors)

Shimadzu/Hitachi

ED-XRF(35万)

50000 yuan/year

160000 yuan/year (2 professional inspectors)

Tianrui/Huawei EDX (100000 yuan)

10000 yuan/year (no other consumables required)

60000 yuan/year (1 full-time inspector can operate 2 instruments)

mercury

cadmium

chromium

Polybrominated biphenyls

Polybrominated diphenyl ether

Rosh2.0

Add 4 new ortho benzenes

DBP

BBP

DEHP

DIBP

Shimadzu PY+GCMS

(1.5 million)

100000 yuan/year

HPLC

(180000)

100000 per year (requires a large amount of reagents and declaration of hazardous materials)

TP30-GCMicro cracking desorption gas chromatography (400000)

5000Yuan/year (only a small amount of quartz injection tube needs to be replaced)

Procurement cost and usage cost

185ten thousand

15Ten thousand per year

20Ten thousand per year

53ten thousand

15ten thousand

16ten thousand

50ten thousand

1.5Ten thousand per year

6Ten thousand per year

Sample practicality

IECThe standard clearly states that only soluble solid samples can be subjected to ultrasonic extraction, while difficult to dissolve or insoluble polymer samples cannot be subjected to ultrasonic extraction. (Generally, 30% of polymer samples in factories are insoluble or difficult to dissolve, in other words, 30% of samples may be misjudged during the sampling process.)

IECThe standard clearly states that only soluble solid samples can be subjected to ultrasonic extraction, while difficult to dissolve or insoluble polymer samples cannot be subjected to ultrasonic extraction. (Generally, 30% of polymer samples in factories are insoluble or difficult to dissolve, in other words, 30% of samples may be misjudged during the sampling process.)

Polymer samples that are soluble, insoluble, or difficult to dissolve are all acceptable (99% of samples from regular factories), and there will be no misjudgment

70%

70%

99%

Separation effect

4Good separation effect of ortho benzene

There are two neighboring benzene compounds that cannot be separated, which affects the results

4Good separation effect of ortho benzene

Is there any standard

Compliant with IEC62321 standard

N/A

Compliant with IEC62321-8 standard

How many things can be done every day

Process 30 samples per day

Process around 5-7 samples per day

Each sample should be sonicated for at least 2 hours, and the sample should be made for 30 minutes (sonication for 2 hours may not necessarily reveal the presence of ortho benzene in many samples)

Process over 50 samples per day

No need for sample pre-treatment, the sample making process is fully automated, and each sample takes 20 minutes to complete

Applying for a wastewater and exhaust gas discharge permit?

Need (complicated procedures)

1Requires a large amount of reagents (such as acetoneAcetonitrile and other reagents require reporting before use, and a professional laboratory needs to be established to pass the environmental impact assessment by regulatory authorities

2A large amount of wastewater and waste liquid are generated, which cannot be treated by oneself. It is necessary to hire a professional hazardous waste company to handle it, which is costly and cumbersome, and requires applying for a hazardous waste discharge permit

Need (complicated procedures)

1Requires a large amount of reagents (such as acetoneAcetonitrile and other reagents require reporting before use,

2A large amount of wastewater and waste liquid are generated, which cannot be treated by oneself. It is necessary to hire a professional hazardous waste company to handle it, which is costly and cumbersome, and requires applying for a hazardous waste discharge permit

No need

This plan does not contain any reagents and will not produce any wastewater or waste liquid,

Set up an environment with a console and air conditioning installed

feature

High procurement cost

complicated operation

High operation and maintenance costs in the later stage

The pre-processing is too complicated

The operator's operation has a significant impact on the results

The sample preparation time is too long and does not have the ability to quickly screen

Low procurement cost;

The screening process is simple and fast;

Low operation and maintenance costs in the later stage

Part Three, Instrument Accuracy and Reliability Test:

Experimental section: Instruments and consumables

1. Gas chromatograph with dual EPC control;

2. HP3000-GC thermal cracking desorption instrument (cracking desorption temperature 200 ℃ -650 ℃);

3. Chromatography workstation (with reverse control function);

4. Capillary ortho benzene column;

5. Nitrogen hydrogen air source;

6. One ten thousandth scale;

Pre processing procedure:

This method does not require pre-treatment. The consumables include a 2.5cm quartz tube, quartz wool, and pre-treatment column. Place the solid sample in the middle of the quartz tube, fix both ends with quartz wool, and then place the prepared sample tube into the heating chamber.

Analysis conditions

Micro cracking program heats up from 200 ℃ to 450 ℃

Micro pyrolysis time 2 minutes

Injection method: Split injection

Liquid injection volume: 1 ul

Solid injection volume: below 5mg

Injection port temperature: 250 ℃

FID detector temperature: 300 ℃

Program heating up to 50 ℃ (hold for 1 minute), increasing to 400 ℃ at a rate of 20 ℃ per minute (hold for 10 minutes)

Name and retention time of each component

name

abbreviation

retention time

Time window strip

remark

Diisobutyl phthalate

DIBP

8.524

0.05

Dibutyl phthalate

DBP

9.041

0.05

Butyl benzyl phthalate

BBP

10.941

0.05

Di (2-ethylhexyl) phthalate

DEHP

11.949

0.05

Results and Discussion:

Standard curve and linear range (detection limit)

Prepare DIBP standard solutions with concentrations of 50ppm, 100ppm, 250ppm, 500ppm, and 1000ppm. Plot standard curves with concentration as the x-axis and quantitative component peak area as the y-axis. The standard curves and linear correlation coefficients are shown below.

The following table shows the comparison of peak height and peak area for 5 different concentration standard samples:

Concentration (ppm)

Peak height (pA)

Peak area (A)

50

2038.7

8472.5

100

2829.6

12607.7

250

5720.6

24674.0

500

12090.8

53037.4

1000

24747.2

120759.3

The detection limit for each component calculated based on a 3x signal-to-noise ratio is 25ppm

Repetition (precision experiment)

The repeatability determination was conducted at the detection limit concentration, and the results are shown below.

RSD%

DIBP

Peak Height

peak area

1

944.8

3484.2

2

1007.3

3638.8

3

903.2

3167.9

4

1205.6

4227.6

RSD%=5.24

The detection limit is 50ppm and the linear correlation coefficient is greater than 0.998, RSD%=5.24, *Requirements for material screening in enterprises.

Rohs2.0 adds 4 rapid detection schemes for phthalates - Baichuan YiqiThe information is provided by Shenzhen Huapu General Technology Co., Ltd. If you would like to learn more aboutRohs2.0 adds 4 rapid detection schemes for phthalates - Baichuan YiqiQuotation, model, parameters and other information, or leave a message for consultation.

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